The book's aim is to inform, to teach, and to correct inaccuracies-it is never boring...It can be thoroughly recommended.
Angewandte Chemie
The book is a first-class scholarly monograph." Faraday Transactions
Scientists in many fields are now expressing considerable interest in non-linearity and the ideas of oscillations and chaos. Chemical reactions provide perfect examples of these phenomena, as oscillating reactions, explosions, ignition, travelling waves, patterns, quasiperiodicity, and chaos are all features of chemical kinetics.^
Now available in paperback, this book introduces non-linear phenomena in chemical kinetics using simple model schemes. These models involve chemical feedback, such as chain branching, autocatalysis, and self-heating. The emphasis is on physical and pictorial representation, and on identifying those gross features which are essential. The experimental conditions under which such behaviour will occur can be predicted using simple mathematical recipes, and these are also included.^
The first part of the book begins with a discussion of long-lived oscillations for autocatalytic or exothermic reactions in closed vessels. Stationary states, bistability, and oscillations in continuous flow reactors and diffusion cells are then considered. This is followed by chemical wave propagation and by pattern selection and oscillations. Complex oscillations, quasiperiodicity, and chemical chaos, either forced or spontaneous, are introduced. Part 2 deals with real experimental systems, describing observed experimental behaviour and its interpretation in terms of the underlying chemical mechanisms or simplified models. The Belousov-Zhabotinskii reactions is discussed in some detail as the most extensively studied system, and the behaviour of important gas phase reactions is presented.
Les mer
The model and experimental examples used in this text should interest research workers in chemical kinetics (physical chemistry) and chemical engineering, as well as mathematicians, biologists, physicists, and physiologists.
Les mer
1. Introduction ; Part 1: The Techniques ; 2. Oscillations in a closed isothermal system ; 3. Oscillations in a closed isothermal system: mathematical analysis ; 4. Thermokinetic oscillations in a closed system ; 5. Hopf bifurcations, the growth of small oscillations, relaxation oscillations, and excitability ; 6. Autocatalysis in well-stirred open systems: the isothermal CSTR ; 7. Reaction in a non-isothermal CSTR: Stationary states and singularity theory ; 8. Oscillatory behaviour in the isothermal CSTR: autocatalytic systems ; 9. Autocatalytic reactions in plug-flow and diffusion reactors ; 10. Chemical diffusion pattern formation (Turing structures) ; 11. Travelling waves ; 12. Heterogeneous reactions ; 13. Complex oscillations and chemical chaos ; Part 2: Experiments ; 14. Experimental systems 1: solution-phase reactions ; 15. Experimental systems 2: gas-phase reactions ; References ; Index
Les mer
The book's aim is to inform, to teach, and to correct inaccuracies-it is never boring...It can be thoroughly recommended.
`I can recommend the book as an appetiser to anyone wishing to enter the fascinating world of chemical oscillations.'
Journal of Fluid Mechanics
`The authors of this volume ... have taken up the challenge of convincing the working chemist that nonlinear dynamical systems theory can be understood in simple terms, and can help with experimental interpretation. ... There is a great deal of material here, and much of it is very interesting and informative. ... I can recommend the book as an appetiser to anyone wishing to enter the fascinating world of chemical oscillations.'
J. Fluid Mech. (1996), vol.314, pp406-410.
Les mer
BL No other single book covers the complex features of chemical reactions in terms of simple unifying themes
BL Covers experimental aspects of gas-phase reactions
BL A source book of applied problems for graduate students in dynamical systems, advanced chemical kinetics, and chemical reactor engineering
Les mer
Peter Gray is also Visiting Professor, University of Leeds
BL No other single book covers the complex features of chemical reactions in terms of simple unifying themes
BL Covers experimental aspects of gas-phase reactions
BL A source book of applied problems for graduate students in dynamical systems, advanced chemical kinetics, and chemical reactor engineering
Les mer
Produktdetaljer
ISBN
9780198558644
Publisert
1994
Utgiver
Vendor
Clarendon Press
Vekt
660 gr
Høyde
233 mm
Bredde
155 mm
Dybde
28 mm
Aldersnivå
P, 06
Språk
Product language
Engelsk
Format
Product format
Heftet
Antall sider
470